====== McEuen Group MSDS Compilation ======

==Please update this information with any new chemicals that are brought into the lab!!==

As of 2014, Cornell EH&S has subscribed to an online MSDS system called [[http://sp.ehs.cornell.edu/lab-research-safety/research-safety/msds/Pages/default.aspx|Chemwatch]].  Make sure to do a vendor search; chemicals for most major vendors can be found on it.

The list below is specific to our lab; most chemicals have two msds sheets available.  One is available as a pdf download, and the other is a link.  MSDS are not regulated, and each one may contain different information.  As such, it is suggested that you view both of the provided MSDS for a chemical to get the best idea possible about potential risks and necessary safety precautions.

=====Procurement of New Chemicals=====
See [[Safety#MSDS and Chemical Inventory|MSDS and Chemical Inventory]].

=====Special and/or Notable Considerations=====

Please view Melina's lab safety presentation!  There is a lot of valuable information.

{{:wiki:finalchemtalksmall.pdf|Lab Safety}}

Key Notes:

  * Always **add acid to water** (as a memory aid, my chem teacher would say, "do as you oughta, add acid to wata" (Do as you ought to, add acid to water)).

  * Don't drink solvents (lab ethanol is full of contaminants).

  * **Acetone and hydrogen peroxide** are catalyzed by acids (e.g. acetic acid, etc) to form acetone peroxide which is 10 times more shock sensitive than nitroglycerin (look up some videos, it's pretty powerful too).

  * **Sodium hydroxide**, besides burning your skin, causing lung damage and blinding you, reacts with magnesium, zinc, tin, chromium, brass, and aluminum to form hydrogen gas.

  * **Dichloromethane** is metabolized into carbon monoxide (which is BAD) and can cause severe eye damage.

  * **DMF** melts plastic and is carcinogenic.

  * **Resorcinol** is incompatible with methanol, strong oxidizers and bases and is poisonous in strong doses of inhalation or skin/eye contact.

  * **Trichloroethylene** is an anesthetic, toxic to liver and kidneys and probably carcinogenic.

  * **DSO** is not very dangerous alone, but DISSOLVES NITRILE GLOVES and carries other chemicals with it.

  * Other info: acids are bad, piranha is bad, hydrogen gas is bad, sealed containers of liquid nitrogen are bad (also, don't take it in the elevator with you).  See the safety presentation for more specific information.

  - Know the risks
  - Plan for an emergency
  - Wear eye protection, appropriate gloves and other safety equipment
  - Never be in the lab alone
  - Know the evacuation plan

== "If you can't be a good example, try to be a horrible warning" - Stephen Fry ==

=====Solvents Cabinet=====

====1-Octanol====

{{:wiki:1-octanol_msds.pdf|1-Octanol}}

====Benzene====

{{:wiki:benzene_msds.pdf|Benzene}}

==== 1165 ====
[[http://grover.mirc.gatech.edu/data/msds/296.html|1165]]

==== 1-Hexadecanethiol ====

[[http://www.asemblon.com/system/files/706017+Rev+1+1-Hexadecanethiol.pdf|1-hexadecanethiol]]

{{:wiki:706017_rev_1_1-hexadecanethiol.pdf|1-hexadecanethiol}}

==== 1-Octadecanethiol ====

{{:wiki:096_-_1-octadecanethiol_-_aldrich.pdf|1-octadecanethiol}}


==== Acetone ====

[[http://www.jtbaker.com/msds/englishhtml/a0446.htm|Acetone]]

{{:wiki:acetonemsds.pdf|Acetone}}


==== Toluene ====

{{:wiki:toluene.pdf|Toluene}}


==== Tetrahydrofuran ====

{{:wiki:tetrahydrofuran.pdf|Tetrahydrofuran}}


==== Benzene-1,3-diol (Resorcinol) ====

[[http://www.jtbaker.com/msds/englishhtml/r3900.htm|Resorcinol]]

{{:wiki:resorcinolmsds.pdf|Recorcinol}}


==== Chloroform ====

[[http://www.jtbaker.com/msds/englishhtml/c2915.htm|Chloroform]]

{{:wiki:chloroformmsds.pdf|Chloroform}}

==== Dichloromethane (Methane Chloride) ====

[[http://www.jtbaker.com/msds/englishhtml/D2895.htm|Dichloromethane]]


{{:wiki:dichloromethanemsds.pdf|Dichloromethane}}

==== Dihydrogen Monoxide (Water) ====

[[http://www.jtbaker.com/msds/englishhtml/w0600.htm|Water]]

{{:wiki:watermsds.pdf|Water}}


==== Dimethyl sulfoxide (DSO) ====

[[http://www.jtbaker.com/msds/englishhtml/d7120.htm|Dimethyl sulfoxide]]

{{:wiki:dmomsds.pdf|Dimethyl Sulfoxide}}

==== Ethanol ====

[[http://fscimage.fishersci.com/msds/89308.htm|Ethanol]]

{{:wiki:ethanolmsds.pdf|Ethanol}}

==== Graphite ====

[[http://www.jtbaker.com/msds/englishhtml/g8122.htm|Graphite]]

{{:wiki:graphitemsds.pdf|Graphite}}

==== 2-Propanol (IPA) ====

[[http://www.jtbaker.com/msds/englishhtml/p6401.htm|IPA]]

{{:wiki:2-propanolmsds.pdf|IPA}}

==== Methanol ====

[[http://www.jtbaker.com/msds/englishhtml/m2015.htm|Methanol]]

{{:wiki:msds_methanol.pdf|Methanol}}

==== N,N-Dimethylformamide ====

[[http://www.jtbaker.com/msds/englishhtml/d6408.htm|N,N-Dimethylformamide]]

{{:wiki:n_n-dimethylformamidemsds.pdf|N,N-Dimethylformamide}}

==== Potassium Hydroxide ====

[[http://www.jtbaker.com/msds/englishhtml/p5884.htm|Potassium Hydroxide]]

{{:wiki:potassiumhydroxidemsds.pdf|Potassium Hydroxide}}

==== Trichloroethylene ====

[[http://www.jtbaker.com/msds/englishhtml/t4940.htm|Trichloroethylene]]

{{:wiki:trichloroethylenemsds.pdf|Trichloroethylene}}

=====Acid Cabinet=====

==== Acetic Acid ====

[[http://www.jtbaker.com/msds/englishhtml/a0326.htm|Acetic Acid]]

{{:wiki:aceticacid_msds.pdf|Acetic Acid}}

==== Gold Etch - TFA ====

{{:wiki:goldetchfta_msds.pdf|Gold Etch}}

==== Chrome Etch 1020 ====

{{:wiki:chromeetch1020_msds.pdf|Chrome Etch}}

==== Hydrochloric Acid (HCl)====

[[http://www.jtbaker.com/msds/englishhtml/h3880.htm|Hydrochloric Acid]]

{{:wiki:hcl_msds.pdf|Hydrochloric Acid}}

==== Sulfuric Acid ====

[[http://www.jtbaker.com/msds/englishhtml/s8234.htm|Sulfuric Acid]]

{{:wiki:sulphuricacid_msds.pdf|Sulfuric Acid}}

====Silicic Acid====


[[http://fscimage.fishersci.com/msds/20680.htm|Silicic Acid]]

{{:wiki:silicicacid_msds.pdf|Silicic Acid}}

==== Urea (crystals) ====

[[http://www.jtbaker.com/msds/englishhtml/u4725.htm|Urea]]

{{:wiki:urea_msds.pdf|Urea}}

=====Base Cabinet=====

==== Ammonium Hydroxide ====

[[http://fscimage.fishersci.com/msds/01260.htm|Ammonium Hydroxide]]

{{:wiki:msds-ammonium_hydroxide.pdf|Ammonium Hydroxide}}

==== Hydrogen Peroxide ====

30% (which is what we have)

[[http://www.jtbaker.com/msds/englishhtml/h4065.htm|Hydrogen Peroxide]]

{{:wiki:h2o2_msds.pdf|Hydrogen Peroxide}}

Lower % (3%)

[[http://www.jtbaker.com/msds/englishhtml/h4070.htm|Hydrogen Peroxide 2]]

==== Sodium Bicarbonate ====

[[http://www.jtbaker.com/msds/englishhtml/s2954.htm|Sodium Bicarbonate]]

{{:wiki:sodiumbicarbonate_msds.pdf|Sodium Bicarbonate}}

==== Sodium Hydroxide ====

[[http://www.jtbaker.com/msds/englishhtml/s4034.htm|Sodium Hydroxide]]

{{:wiki:naoh_msds.pdf|Sodium Hydroxide}}

====Sodium Silicate Solution====


[[http://www.avantormaterials.com/documents/MSDS/USA/English/S4982_msds_us_Default.pdf|Sodium Silicate]]

{{:wiki:sodiumsilicate_msds.pdf|Sodium Silicate}}



=====Other/No Home=====



==== Ferric Chloride ====
[[http://www.jtbaker.com/msds/englishhtml/f1060.htm|Ferric Chloride]]

{{:wiki:ferricchloride_msds.pdf|Ferric Chloride}}

==== Ferric Chloride Solution (copper etchant type Ce-200) ====

[[http://www.jtbaker.com/msds/englishhtml/f1080.htm|Ferric Chloride Solution]]

{{:wiki:ferricchloridesolution_msds.pdf|Ferric Chloride Solution}}

Ce-200 actually has some additionally additives, see this msds for the actual copper etch.

[[http://mems.uwaterloo.ca:8080/download/attachments/917527/Copper+Etchant+Type+100-200.pdf?version=1|Copper Etch]]

==== Copper Etchant type 49-1 ====
{{:wiki:copperetchant49-1.pdf|}}

==== Copper Etchant type APS-100 ====
{{:wiki:copper_etch_aps-100.pdf|}}

==== Piranha ====

{{:wiki:piranha_msds.pdf|Piranha1}}

{{:wiki:piranha_msds2.pdf|Piranha2}}

==== Polyvinylpyrrolidone ====

[[http://www.jtbaker.com/msds/englishhtml/p5290.htm|Polyvinylpyrrolidone]]

{{:wiki:polyvinylpyrrolindone_msds.pdf|Polyvinylpyrrolidone}}

=====Compressed Gasses=====

==== 2% Oxygen Balance Argon ====

See argon below.

{{:wiki:oxygen_msds1.pdf|Oxygen1}}

{{:wiki:oxygen_msds2.pdf|}}

==== Argon ====

[[http://www.iigas.com/argon_msds.htm|Argon]]

{{:wiki:argon_msds.pdf|Argon}}

==== Ethylene (Ethene) ====

{{:wiki:ethylene_msds1.pdf|Ethylene1}}

{{:wiki:ethylene_msds2.pdf|Ethylene2}}

==== Hydrogen ====

[[http://www.acialloys.com/msds/h.html|Hydrogen]]

{{:wiki:hydrogen_msds.pdf|Hydrogen}}

==== Methane ====

[[http://avogadro.chem.iastate.edu/MSDS/methane.pdf|Methane]]

{{:wiki:methane_msds.pdf|Methane}}

==== Nitrogen ====

{{:wiki:nitrogen1.pdf|Nitrogen1}}

{{:wiki:nitrogen2.pdf|Nitrogen2}}

=====Cryogens=====

==== Liquid Helium ====

{{:wiki:l-helium_msds.pdf|Liquid Helium 1}}

{{:wiki:l-helium2_msds.pdf|Liquid Helium 2}}

==== Liquid Nitrogen ====

[[http://www.uigi.com/MSDS_liquid_N2.html|Liquid Nitrogen]]

[[http://stores.biochem.uiowa.edu/Pages/ln2msds.htm|Liquid Nitrogen 2]]

{{:wiki:liquidnitrogen_msds.pdf|Liquid Nitrogen pdf}}

=====Dry Box=====

====L-Methionine===

{{:wiki:l-methionine_msds.pdf|L-Methionine}}

==== [5,6] Fullerene - C70 ====

==== 1-Pyrenebutyric acid N-hydroxysuccinimide ester ====

==== Buckminsterfullerene ====

==== Chromium hexacarbonyl ====

==== Cobalt Chloride (crystals) ====

==== Diethyl Ether with 5nm Fe crystals (one sample) ====

==== Diphenylphosphinobenzene-m-sulfonic acid sodium salt ====

==== Hydroxylamine hydrochloride ====

==== Hydroxypropyl Cellulose ====

==== Iron(III) chloride ====

==== L-absorbic acid ====

==== Lithium perchlorate ====

==== Magnesium Sulfate ====

==== Nickel(II) perchlorate hexahydrate ====

==== poly(ethylene) oxide ====

==== Polyethylenimine ====

==== Polyvinyl alcohol ====

==== Potassium Chloride ====

==== Potassium tetrachloroaurate (III) ====

==== Sodium Acetate ====

==== Sodium chlorite (crystal) ====

==== Sodium citrate-dihydrate (crystal) ====

==== Sodium Flouride ====

==== Sodium Nitrate ====

==== Sodium Sulfate ====

==== Sodium thiosulfate pentahydrate ====
